Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates,nicotianamine, and phytosiderophore,and new Fe isotopic measurements in higher plants     

Frédéric Moynier  Toshiyuki Fujii  Kun Wang  Julien Foriel 《Comptes Rendus Geoscience》2013,345(5-6):230-240

Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (⁵⁶Fe/⁵⁴Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate₂ and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ⁵⁶Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.  相似文献   

Nuclear field shift in natural environments     

Frédéric Moynier  Toshiyuki Fujii  Gregory A. Brennecka  Sune G. Nielsen 《Comptes Rendus Geoscience》2013,345(3):150-159

The nuclear field shift (NFS) is an isotope shift in atomic energy levels caused by a combination of differences in nuclear size and shape and electron densities at the nucleus. The effect of NFS in isotope fractionation was theoretically established by Bigeleisen in 1996 [Bigeleisen J. (1996) J. Am. Chem. Soc. 118:3676–3680] and has been analytically measured in laboratory chemical exchange reactions. More recently, some isotopic variations of heavy elements (Hg, Tl, U) measured in natural systems as well as isotopic anomalies measured for lower-mass elements in meteorites have been attributed to the NFS effect. These isotopic variations open up new and exciting fields of investigations in Earth sciences. In this paper, we review the different natural systems in which NFS has been proposed to be the origin of isotopic variations.  相似文献   

Cross-shore variation of long-term average longshore current velocity in the nearshore zone     

Yoshiaki Kuriyama  Yoshimasa Ito  Shinichi Yanagishima 《Continental Shelf Research》2008

The cross-shore variation of long-term average longshore current velocity was investigated on the basis of a 15-year data set of longshore current, wave and wind. The longshore current velocities were measured once a day along a 427-m-long pier. The results show that the direction of the long-term average longshore current velocity away (>200 m) from the shore was the opposite to that near the shore. The southward current was dominant offshore, whereas the northward current was dominant near the shore. The cross-shore variation of the long-term average longshore current velocity was formed owing to a difference between the wave and wind conditions when the northward and southward currents developed. When the northward current developed, the offshore wave height was relatively small and the frequency of the southward wind velocity was almost equal to that of the northward one. As a result, the northward current developed only near the shore and decayed outside the narrow surf zone. On the other hand, when the southward current developed, the offshore wave height was relatively large and the southward wind velocity was predominant, which resulted in the southward current developing not only in the wide surf zone but also outside the surf zone. The superposition of the two cross-shore variations produced a cross-shore variation of the long-term average longshore current velocity with a northward velocity near the shore and a southward velocity away from the shore.  相似文献   

SHRIMP zircon and EPMA monazite dating of granitic rocks from the Maizuru terrane, southwest Japan: Correlation with East Asian Paleozoic terranes and geological implications   总被引：1，自引：0，他引：1  

Masahiro  Fujii  Yasutaka  Hayasaka  Kentaro  Terada 《Island Arc》2008,17(3):322-341

Abstract The Maizuru terrane, distributed in the Inner Zone of southwest Japan, is divided into three subzones (Northern, Central and Southern), each with distinct lithological associations. In clear contrast with the Southern zone consisting of the Yakuno ophiolite, the Northern zone is subdivided into the western and eastern bodies by a high-angle fault, recognized mainly by the presence of deformed granitic rocks and pelitic gneiss. This association suggests an affinity with a mature continental block; this is supported by the mode of occurrence, and petrological and isotopic data. Newly obtained sensitive high mass-resolution ion microprobe (SHRIMP) zircon U–Pb ages reveal the intrusion ages of 424 ± 16 and 405 ± 18 Ma (Siluro–Devonian) for the granites from the western body, and 249 ± 10 and 243 ± 19 Ma (Permo–Triassic) for the granodiorites from the eastern body. The granites in the western body also show inherited zircon ages of around 580 and 765 Ma. In addition, electron probe microanalysis (EPMA) monazite U–Th–total Pb dating gives around 475–460 Ma. The age of intrusion, inherited ages, mode of occurrence, and geological setting of the Siluro–Devonian granites of the Northern zone all show similarities with those of the Khanka Massif, southern Primoye, Russia, and the Hikami granitic rocks of the South Kitakami terrane, Northeast Japan. We propose that both the Siluro–Devonian and Permo–Triassic granitic rocks of the Northern zone are likely to have been juxtaposed through the Triassic–Late Jurassic dextral strike-slip movement, and to have originated from the Khanka Massif and the Hida terrane, respectively. This study strongly supports the importance of the strike-slip movement as a mechanism causing the structural rearrangement of the Paleozoic–Mesozoic terranes in the Japanese Islands, as well as in East Asia.  相似文献   

Development of a GPGPU-parallelized hybrid finite-discrete element method for modeling rock fracture     

Daisuke Fukuda  Mojtaba Mohammadnejad  Hongyuan Liu  Sevda Dehkhoda  Andrew Chan  Sang-Ho Cho  Gyeong-Jo Min  Haoyu Han  Jun-ichi Kodama  Yoshiaki Fujii 《国际地质力学数值与分析法杂志》2019,43(10):1797-1824

The hybrid finite-discrete element method (FDEM) is widely used for engineering applications, which, however, is computationally expensive and needs further development, especially when rock fracture process is modeled. This study aims to further develop a sequential hybrid FDEM code formerly proposed by the authors and parallelize it using compute unified device architecture (CUDA) C/C++ on the basis of a general-purpose graphics processing unit (GPGPU) for rock engineering applications. Because the contact detection algorithm in the sequential code is not suitable for GPGPU parallelization, a different contact detection algorithm is implemented in the GPGPU-parallelized hybrid FDEM. Moreover, a number of new features are implemented in the hybrid FDEM code, including the local damping technique for efficient geostatic stress analysis, contact damping, contact friction, and the absorbing boundary. Then, a number of simulations with both quasi-static and dynamic loading conditions are conducted using the GPGPU-parallelized hybrid FDEM, and the obtained results are compared both quantitatively and qualitatively with those from either theoretical analysis or the literature to calibrate the implementations. Finally, the speed-up performance of the hybrid FDEM is discussed in terms of its performance on various GPGPU accelerators and a comparison with the sequential code, which reveals that the GPGPU-parallelized hybrid FDEM can run more than 128 times faster than the sequential code if it is run on appropriate GPGPU accelerators, such as the Quadro GP100. It is concluded that the GPGPU-parallelized hybrid FDEM developed in this study is a valuable and powerful numerical tool for rock engineering applications.  相似文献   

Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters     

Manabu Fujii  Andrew L. Rose  Tatsuo Omura 《Geochimica et cosmochimica acta》2008,72(5):1335-1349

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.  相似文献   

Stress-induced crack path in Aji granite under tensile stress     

Yozo Kudo  Osam Sano  Naokuni Murashige  Yoshiaki Mizuta  Koji Nakagawa 《Pure and Applied Geophysics》1992,138(4):641-656

The double-torsion test using Aji granite was carried out to investigate the interaction between stress-induced crack path and mineral grains. Crack velocities were controlled at range 10^–7 m/s to 10^–1 m/s. After the stressed specimens were dyed, we checked the crack path by thin section analysis, using an optical microscope. The stress-induced crack path was divided into two types, transgranular and intergranular cracks, and each path was subdivided with respect to mineral grains. In spite of the extensive range of crack velocities, the ratios between the transgranular and intergranular crack lengths did not change. The crack paths were all jagged, and often showed detour around the grain boundary when faced with obstacles like hard grains or preexisting cracks. That is to say, quartz grain played an important role as an obstacle. Feldspar grain could change the crack path because of its cleavage plane. Biolite grain had a serious effect on the path even if its constitution ratio is very small. Fractal dimensions of the crack paths were calculated by three methods, as indicators of surface roughness. The fractal dimensions were shown in a slight trend with the change of crack velocity. This trend can be explained from the point of limited cracking rate in stress corrosion.  相似文献   

Adjustment of Wind Waves to Sudden Changes of Wind Speed   总被引：1，自引：0，他引：1  

Takuji Waseda  Yoshiaki Toba  Marshall P. Tulin 《Journal of Oceanography》2001,57(5):519-533

An experiment was conducted in a small wind-wave facility at the Ocean Engineering Laboratory, California, to address the following question: when the wind speed changes rapidly, how quickly and in what manner do the short wind waves respond? To answer this question we have produced a very rapid change in wind speed between U _low (4.6 m s^?1) and U _high (7.1 m s^?1). Water surface elevation and air turbulence were monitored up to a fetch of 5.5 m. The cycle of increasing and decreasing wind speed was repeated 20 times to assure statistical accuracy in the measurement by taking an ensemble mean. In this way, we were able to study in detail the processes by which the young laboratory wind waves adjust to wind speed perturbations. We found that the wind-wave response occurs over two time scales determined by local equilibrium adjustment and fetch adjustment, Δt ₁/T = O(10) and Δt ₂/T = O(100), respectively, in the current tank. The steady state is characterized by a constant non-dimensional wave height (H/gT ² or equivalently, the wave steepness for linear gravity waves) depending on wind speed. This equilibrium state was found in our non-steady experiments to apply at all fetches, even during the long transition to steady state, but only after a short initial relaxation Δt ₁/T of O(10) following a sudden change in wind speed. The complete transition to the new steady state takes much longer, Δt ₂/T of O(100) at the largest fetch, during which time energy propagates over the entire fetch along the rays (dx/dt = c _g) and grows under the influence of wind pumping. At the same time, frequency downshifts. Although the current study is limited in scale variations, we believe that the suggestion that the two adjustment time scales are related to local equilibrium adjustment and fetch adjustment is also applicable to the ocean.  相似文献   

Nutrient regeneration at bottom after a massive spring bloom in a subarctic coastal environment,Funka Bay,Japan     

Isao Kudo  Takeshi Yoshimura  Choon-Weng Lee  Mitsuru Yanada  Yoshiaki Maita 《Journal of Oceanography》2007,63(5):791-801

Nutrient regeneration and oxygen consumption after a spring bloom in Funka Bay were studied on monthly survey cruises from February to November 1998 and from March to December 1999. A high concentration of ammonium (more than 4 μmol l⁻¹) was observed near the bottom (80–90 m) after April. Phosphate and silicate gradually accumulated and dissolved oxygen decreased in the same layer. Salinity near the bottom did not change until summer, leading to the presumption that the system in this layer is semi-closed, so regenerated nutrients were preserved until September. Nitrification due to the oxidation of ammonium to nitrate was observed after June. Nitrite, an intermediate product, was detected at 4–7 μmol L⁻¹ in June and July 1999. Assuming that decomposition is a first order reaction, the rate constant for decomposition of organic nitrogen was determined to be 0.014 and 0.008 d⁻¹ in 1998 and 1999, respectively. The ammonium oxidation rate increased rapidly when the ambient ammonium concentration exceeded 5 μmol L⁻¹. We also performed a budget calculation for the regeneration process. The total amount of N regenerated in the whole water column was 287.4 mmol N m⁻² in 4 months, which is equal to 22.8 gC m⁻², assuming the Redfield C to N ratio. This is 34% of the primary production during the spring bloom and is comparable to the export production of 25 gC m⁻² measured by a sediment trap at 60 m (Miyake et al., 1998).  相似文献   

The steepness and shape of wind waves     

Richard J. Bailey  Ian S. F. Jones  Yoshiaki Toba 《Journal of Oceanography》1991,47(6):249-264

Variations are found in the shape and the steepness of wind-generated surface gravity waves between very young waves, such as seen in a laboratory tank, and larger waves of various wave ages encountered at sea as the result of wind stress over larger fetches. These differences in the characteristic shape of wind waves are presented as a function of the wave age. The wave steepness is also expressed as a function of wave age, the measurement of which is consistent with the 3/2-power law connecting wave height and characteristic period, normalized by the air friction velocity.  相似文献